Article citationsMore>>
Brazhkin, V.V., Fomin, Y.-D., Lyapin, A.G., Ryzhov, V. N. and Tsiok, E.N. (2011) Widom line for the liquid-gas transition in Lennard-Jones system. The Journal of Physical Chemistry B, 115, 14112-14115.
doi:10.1021/jp2039898
has been cited by the following article:
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TITLE:
Fluid phases of argon: A debate on the absence of van der Waals’ “critical point”
AUTHORS:
Leslie V. Woodcock
KEYWORDS:
Critical Point; Supercritical Fluids; Liquid Phase
JOURNAL NAME:
Natural Science,
Vol.5 No.2,
February
18,
2013
ABSTRACT: A phase diagram of
argon based upon percolation transition loci determined from literature
experimental p-V isotherms, and simulation values using a Lennard-Jones model
shows three fluid phases. The liquid phase spans all temperatures, from a
metastable amorphous ground state at 0K, to ultra-high T. There is a supercritical mesophase bounded by percolation transition
loci, and a gas phase. Intersection of two percolation loci in the p-T plane thermodynamically defines a critical line between two coexisting gas and
liquid critical states at T = Tc, and the single mesophase
for T > Tc. A debate on the absence of a van der Waals critical
point in the Gibbs p-T density surface is appended.