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R. M. Saleh, A. A. Ismail and A. H. El Hosary “Corrosion Inhibi-tion by Naturally Occurring Substances. The Effect of Aqueous Extracts of Some Leaves and Fruit Peels on the Corrosion of Steel, Al, Zn and Cu in Acids,” British Corrosion Journal, Vol. 17, No. 3, 1982, pp. 131-135.

has been cited by the following article:

• TITLE: Synergistic Effect of Allium cepa-Zn2+ System on the Corrosion of Carbon Steel in Ground Water

  AUTHORS: A. John Amalraj, J. Wilson Sahayaraj, A. Peter Pascal Regis, Arockia Sahayaraj, P. Pandian, P. Johnraj, A. Kasthuri, C. Kumar

  KEYWORDS: Carbon Steel; Allium cepa; Corrosion Inhibition Efficiency; Ground Water

  JOURNAL NAME: Engineering, Vol.5 No.2, February 6, 2013

  ABSTRACT: The corrosion inhibition efficiency (IE) of an aqueous extract Allium cepa (onion) in controlling the corrosion of carbon steel ground water in absence and presence of with Zn2+ has been studied by weight loss method. The formulation consisting of 3 mL Allium cepa extract, 50 ppm of Zn2+ and 50 ppm of sodium pattassium tartarate which offers 97% inhibition efficiency. The synergistic effect exists between onion-Zn2+-tartarate system. The addition of N-cetyl-N,N,N- trimethylammonium bromide on onion-Zn2+-tartarate system does not change the excellent inhibition efficiency. Polarization study shows that the onion-Zn2+-tartarate system functions as a cathodic inhibitor. AC impedance spectra reveals that a protective film is formed on the metal surface. The UV fluorescent spectra indicate the possibility of formation of Fe2+-onion complex and also Zn2+-onion complex in solution. Thus the protective film is found to be UV fluorescent.