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S. K. Lim, J. W. Kim, I. Chim, Y. K. Kwon and H. J. Choi, “Preparation and Interaction Characteristics of Organically Modified Montmorillonite Nanocomposite with Miscible Polymer Blend of Poly(Ethylene Oxide) and Poly(Methyl Methacrylate),” Chemistry of Materials, Vol. 14, No. 5, 2002, pp. 1989-1994. doi:10.1021/cm010498j

has been cited by the following article:

• TITLE: Preparation and Characterization of Clay (Maghnite-H)/Poly(3,4-Ethylenedioxythiophene) Composites

  AUTHORS: Affaf Megherbi, Rachid Meghabar, Mohammed Belbachir

  KEYWORDS: Poly(3, 4-Ethylenedioxythiophene); PEDOT; Clay; Maghnite-H; Montmorillonite

  JOURNAL NAME: Journal of Surface Engineered Materials and Advanced Technology, Vol.3 No.1, January 29, 2013

  ABSTRACT: Composites of Maghnite-H, a Montmorillonite sheet silicate clay, exchanged with protons, and Poly(3,4-ethylenedioxythiophene) (PEDOT) were prepared by in situ chemical polymerization of the 3,4-ethylenedioxythiophene, without the use of solvent or oxidant. The effect of changing monomer/clay ratio was studied and the resultant composite structures were characterized by Inferred spectroscopy, 27Al and 13CSolid-State NMR spectroscopy, scanning electron microscopy and powder X-ray diffraction. All analyses are consistent with a structure were the polymer is (partially) intercalated into the clay structure, which in favourable cases lead to exfoliation. The presence of the clay in the polymer leads to a desired increase in thermal stability as witnessed by thermogravimetry.