J. H. Espenson, “Formation Rates of Monosubstituted Chromium(III) Complexes in Aqueous Solution,” Inorganic Chemistry, Vol. 8, No. 7, 1971, pp. 1554-1556. doi:10.1021/ic50077a047
has been cited by the following article:
TITLE: Kinetics and Mechanism of Interaction between Chromium(III) and Ethylenediaminetetra-3-Propinate in Aqueous Acidic Media
AUTHORS: Michel. F. Abdel-Messih
KEYWORDS: Kinetic; Mechanism; Substitution; Ethylenediaminetetra-3-Propinate; Chromium(III)
JOURNAL NAME: Advances in Chemical Engineering and Science, Vol.3 No.1, January 24, 2013
ABSTRACT: The kinetics of the formation of 1:1 complex of chromium(III) with ethylenediaminetetra-3-propinate (EDTP) was followed spectrophotometrically at lmax = 557 nm. The reaction was found to be first order in chromium(III) and was accelerated by EDTP. Increasing the pH from 3.3 to 4.7 accelerated the reaction rate, the reaction rate was retarded by increasing ionic strength and dielectric constant of the reaction medium. A mechanism was suggested to account for the results obtained which involves ion pair formation between the various species of the reactants. Values of the activation parameters obtained indicate an associative mechanism.