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Gur'eva, Y.A., Zalevskaya, O.A., Frolova, L.L., Alexeev, I.N. and Kutchin, A.V. Chiral imines and amines on the basis of 2α-hydroxypinan-3-one. Chemistry of Natural Compounds, in press.

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• TITLE: Chiral palladium complexes based on derivatives of benzylamine and 2α-hydroxypinan-3-one

  AUTHORS: Olga A. Zalevskaya, Yana A. Gur'eva, Larisa L. Frolova, Igor N. Alekseev, Alexander V. Kutchin

  KEYWORDS: Palladium Complexes; Cyclopalladation; Chiral Imine; Amine

  JOURNAL NAME: Natural Science, Vol.2 No.11, November 30, 2010

  ABSTRACT: Synthesized and characterized new chiral palladium complexes, some of which contain asymmetric donor nitrogen atom. Nitrogen-containing derivatives (+) - and (-)-2α-hydroxypinan-3-one- (1R,2R,5R)-3-(benzylimino)-2,6,6-trimethylbicy- clo[3.1.1]heptane-2-ol (HL1), (1S,2S,3S,5S)-3- (benzylamino)-2,6, 6-trimethylbicyclo[3.1.1]- heptane-2-ol (HL2), (1R,2R,5R)-3-((S)-α-methyl- benzylimino)-2,6,6-trimethylbicyclo[3.1.1]- heptane-2-ol (HL3), (1R,2R,3R,5R)-3-((S)-α-methyl- benzylamino)-2,6,6-trimethylbicyclo[3.1.1]- heptane-2-ol (HL4) -were studied as optically active ligands.