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Sherman and Jonathan, “Nanoparticulate Titanium Dioxide Coatings, and Processes for the Production and Use thereof,” US Patent No. 736738, 2003.

has been cited by the following article:

• TITLE: Augmentation of Multifunctional Properties of Cellulosic Cotton Fabric Using Titanium Dioxide Nanoparticles

  AUTHORS: Mohamed Gouda, Abdullah Ibrahim Aljaafari

  KEYWORDS: Cellulosic Cotton Fabric; TiO2-Nanoparticles; UV-Protection; Self-Cleaning; Antibacterial Properties

  JOURNAL NAME: Advances in Nanoparticles, Vol.1 No.3, November 30, 2012

  ABSTRACT: Titanium dioxide nanoparticle was synthesized by the reduction of titanium tetrachloride using borohydride, water as solvent, and polyvinyl-pyrrolidone as stabilizer. The average size of nano-TiO2 is estimated to be 5 - 10 nm using a transmission electron microscope (TEM); this was confirmed by X-ray diffraction and UV-Vis spectroscopy. Nano-TiO2 was impregnated into cotton fabric to impart multifunctional properties and this was confirmed by scanning electron microscope and scanning electron microscope coupled with high energy distribution X-Ray (SEM-EDX). The TiO2 nanoparticles loaded cotton fabrics showed excellent antibacterial activity against two representative bacteria, Staphylococcus aureus (Gram positive) 96.6% and Klebsiella pneumonia (Gram negative) 95.2%. Also, TiO2 nanoparticles enhanced the self-cleaning and the protection of cotton fabrics against UV radiation in comparison with the untreated cotton fabrics. The TiO2 nanoparticles were durable in-situ cotton fabrics even after 20 laundering wash cycles.