Article citationsMore>>
H. Iwakuni, Y. Shinmyou, H. Yano, K. Goto, H. Matsumoto and T. Ishihara, “Effects of Added CO2 and H2 on the Direct Decomposition of NO over BaMnO3-Based Perovskite Oxide,” Bulletin of the Chemical Society of Japan, Vol. 81, No. 9, 2008, pp. 1175-1182.doi:10.1246/bcsj.81.1175
has been cited by the following article:
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TITLE:
Direct Decomposition of NO into N2 and O2 Over C-type Cubic Y2O3-Tb4O7-ZrO2
AUTHORS:
Toshiyuki Masui, Shunji Uejima, Soichiro Tsujimoto, Nobuhito Imanaka
KEYWORDS:
Nitrogen Monoxide; Direct Decomposition; Catalyst; Rare Earth Oxide; C-type Cubic Structure
JOURNAL NAME:
Materials Sciences and Applications,
Vol.3 No.10,
October
22,
2012
ABSTRACT: Catalytic activities for direct NO decomposition were investigated over C-type cubic Y2O3–Tb4O7–ZrO2 prepared by a coprecipitation method. The NO decomposition activity was enhanced by partial substitution of the yttrium sites with terbium in a (Y0.97Zr0.03)2O3.03 catalyst, which shows high NO decomposition activity. Among the catalysts synthesized in this study, the (Y0.67Tb0.30Zr0.03)2O3.33 catalyst exhibited the highest NO decomposition activity; NO conversion to N2 was as high as 67% at 900℃ in the absence of O2 (NO/He atmosphere), and a relatively high conversion ratio was observed even in the presence of O2 or CO2, compared with those obtained over conventional direct NO decomposition catalysts. These results indicate that the C-type cubic Y2O3–Tb4O7–ZrO2 catalyst is a new potential candidate for direct NO decomposition.