Article citationsMore>>

Hoshino, M., Sonoki, H., Miyazaki,Y., Iimura, Y. and Yamamoto, K. (2000) Structure and photo chemistry of dicyanocobalt(III) tetraphenyl porphyrin. Photochromic reaction caused by photodissociation of axial ligand. Inorganic Chem istry, 39, 4850-4857. HUdoi: 10.1021/ic000408xUH

has been cited by the following article:

• TITLE: Spectroscopic and molecular structure characterization of the bis(2-aminophenol)(5, 10, 15, 20-tetraphenylporphyrinato) cobalt(II) complex

  AUTHORS: Yassin Belghith, Anissa Mansour, Jean-Claude Daran, Habib Nasri

  KEYWORDS: Meso-Tetraphenylporphyrin Cobalt(II); 2-Aminophenol Cobalt(II) Complex; X-Ray Molecular Structure

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.2 No.4, October 16, 2012

  ABSTRACT: The reaction of the cobalt(II) meso-tetraphenylporphyrin (TPP) starting material with an excess of 2-aminophenol (Hon) in organic solvents, yields the cobalt(II) porphyrin species [CoII(TPP)(Hon)2] (1). This compound has been characterized by UV-vis., IR, MSI MS and 1H NMR spectroscopy. The UV-vis data and especially the proton NMR results, for the isolated product, indicated that complex 1 is a Co(II) mesoporphyrin derivative.The X-ray molecular structure of the title compound bis(2-aminophenol) (tetraphenylporphyrinato) cobalt(II) has been determined. This structure is the first one reported of a metalloporphyrin with a 2-aminophenol axial ligand species. The central metal is hexacoordinated by the four nitrogen atoms of the pyrrole rings and the nitrogen atoms of the two Hon trans axial ligands.