Article citationsMore>>

Mansour, A. and Nasri, H. (2012) “Synthesis, crystal structure and spectroscopic characterization of 1D Co(II) coordination polymers {[CoII(α,β,α,β-TpivPP)(μ-4,4’-bp y)2]}n and {[CoII(TPP)(μ-4,4’-bpy)2]}n with the (a,b,a,btetrakis(o-pivalamidophenyl)porphyrin) a,b,a,b-TpivPP) and the tetraphenylporphyrin (TPP). In press.

has been cited by the following article:

• TITLE: Spectroscopic and molecular structure characterization of the bis(2-aminophenol)(5, 10, 15, 20-tetraphenylporphyrinato) cobalt(II) complex

  AUTHORS: Yassin Belghith, Anissa Mansour, Jean-Claude Daran, Habib Nasri

  KEYWORDS: Meso-Tetraphenylporphyrin Cobalt(II); 2-Aminophenol Cobalt(II) Complex; X-Ray Molecular Structure

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.2 No.4, October 16, 2012

  ABSTRACT: The reaction of the cobalt(II) meso-tetraphenylporphyrin (TPP) starting material with an excess of 2-aminophenol (Hon) in organic solvents, yields the cobalt(II) porphyrin species [CoII(TPP)(Hon)2] (1). This compound has been characterized by UV-vis., IR, MSI MS and 1H NMR spectroscopy. The UV-vis data and especially the proton NMR results, for the isolated product, indicated that complex 1 is a Co(II) mesoporphyrin derivative.The X-ray molecular structure of the title compound bis(2-aminophenol) (tetraphenylporphyrinato) cobalt(II) has been determined. This structure is the first one reported of a metalloporphyrin with a 2-aminophenol axial ligand species. The central metal is hexacoordinated by the four nitrogen atoms of the pyrrole rings and the nitrogen atoms of the two Hon trans axial ligands.