Article citationsMore>>
I. M. Reaney, K. Brooks, R. Klissurska, C. Pawlaczyk and N. Setter, “Use of transmission electron microscopy for the characterization of rapid thermally annealed, solution-gel, lead zirconate titanate films”, Journal of the American Ceramic Society, Vol. 77, No. 5, 1994, 1209-1216. doi:10.1111/j.1151-2916.1994.tb05394.x
has been cited by the following article:
-
TITLE:
Phase Transformations in PZT Thin Films Prepared by Polymeric Chemical Method
AUTHORS:
Elton C. Lima, Eudes Borges Araújo
KEYWORDS:
PZT; Thin Films; Phase Transformation
JOURNAL NAME:
Advances in Materials Physics and Chemistry,
Vol.2 No.3,
September
28,
2012
ABSTRACT: Lead zirconate titanate Pb(Zr0.50Ti0.50)O3 (PZT) thin films were deposited by a polymeric chemical method on Pt(111)/ Ti/SiO2/Si substrates to understand the mechanisms of phase transformations in these films. PZT films pyrolyzed at temperatures higher than 350℃ present a coexistence of pyrochlore and perovskite phases, while only perovskite phase is present in films pyrolyzed at temperatures lower than 300℃. For films where the pyrochlore and perovskite phase coexists the amount of pyrochlore phase decreases from top surface to the bottom film-electrode interface and the PZT structure near top surface are Ti-rich compositions while near the bottom film-electrode interface the compositions are Zr-rich. For pyrochlore-free PZT thin film, a small (100) orientation tendency near the film-electrode interface was observed.