Article citationsMore>>

S. A. Bulgakova, E. S. Volgutova, E. A. Kiseleva, I. E. Khokhlova and Y. D. Semchikov, “Controlled Radical Polymerization of Methyl Methacrylate in the Presence of Azobisisobutyronitrile, Iron(III) Chloride, and the Reducing Agent 1-Acetyl-2-phenylhydrazine in Dimethylformamide,” Polymer Science Series B (Russia), Vol. 53, No. 11-12, 2011, pp. 563-567. doi:10.1134/S1560090411110017

has been cited by the following article:

• TITLE: Iron(III)-Mediated AGET ATRP of Methyl Methacrylate in the Absence of Additional Ligand

  AUTHORS: Svetlana A. Bulgakova, Evgeniya S. Volgutova, Irina E. Khokhlova

  KEYWORDS: Atom Transfer Radical Polymerization; Methyl Methacrylate; Iron; Ligand

  JOURNAL NAME: Open Journal of Polymer Chemistry, Vol.2 No.3, August 31, 2012

  ABSTRACT: The atom transfer radical polymerization on the mechanism of activator generation by electron transfer (AGET ATRP) of methyl methacrylate (MMA) in N,N-dimethylformamide (DMF) in the presence of the catalytic systems, namely, CCl4-FeCl3-1-acetyl-2-phenylhydrazine (APH) and CCl4-FeCl3-ascorbic acid (AA) is reported. The living feature of this process was confirmed by obtaining well-defined polymers with controlled molecular weight, narrow molecular weight distribution, and a chain-extension experiment. Both reducing agents, an APH as well as an AA, possess the equal kinetic activitis.