TITLE:
The Influence of γ-Irradiation on Structuration in Solutions of BNR and Properties of Films
AUTHORS:
Shiraz M. Mammadov, Adil А. Garibov, Оktay A. Аkparov, Sehrana A. Rzayeva, Аkif K. Salehov, Sahile S. Ahmadova
KEYWORDS:
Cross-Linking; Solvent; Rheology; Relaxation; Spectrometer; Radiation; Viscosity; Irradiation
JOURNAL NAME:
Open Journal of Physical Chemistry,
Vol.2 No.3,
August
31,
2012
ABSTRACT: Studied influence of γ-irradiation on stucturation in butadiene nitrile rubber solution and films properties studied also. Structuration in solutions has defined by rheological method with rotation viscometer. Shown influence of solvent nature (methyl ethyl ketene: toluene) to strength properties and structures of films obtained from this solvents. It has been found that during irradiation of solvent, films and butadiene nitrile rubber solution characteristic viscosity η increased, increasing of Huggins constant (К') observed as well. Changing of spatial mesh of polymers occurs at the cost of changed size of macromolecule balls. Shown, that in the issue of crossing the properties including thermo dynamical features of films and butadiene nitrile rubber solution has changed.