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Kou, H.Z., Jiang, Y.B. and Cui, A.L. (2005) Two-dimensional coordination polymers exhibiting antiferromagnetic Gd(III)-Cu(II) coupling. Crystal Growth & Design, 5, 77-79. doi:10.1021/cg049897s

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• TITLE: Metal-organic frameworks derived from divalent metals and 4-(1H-1, 2, 4-triazol-1-yl)benzoic acid

  AUTHORS: Jia Li, Gao Zhang, Yan-Tao Li, Xin Wang, Jian-Qi Zhu, Yun-Qi Tian

  KEYWORDS: Coordination Polymers; 4-(1H-1, 2, 4-triazol-1-yl)benzoic Acid; Crystal Structure; Cadmium; Copper

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.2 No.3, June 18, 2012

  ABSTRACT: Two inorganic-organic coordination polymers, [Cd(TBA)2]·3H2O (1) and [Cu(TBA)2]·2H2O (2) have been synthesized by reaction of the metal ions of Cd(II) and Cu(II) with the ligand HTBA [HTBA = 4- (1H-1, 2, 4-triazol-1-yl)benzoic acid] under solvothermal condition. The compounds were characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy, X-ray powder diffraction (XRPD), and thermo gravimetric analysis (TGA). The structural analyses reveal the two independent polymers exhibit different structures. Complex 1 exhibits a 3D framework with 1D channels, and complex 2 shows a 2-fold interpenetrating 3D diamond net.