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Chen, J., Fischer, K. and Gmehling, J. (2002) Modification of PSRK Mixing Rules and Results for Vapor-Liquid Equilibria, Enthalpy of Mixing and Activity Coefficients at Infinite Dilution. Fluid Phase Equilibria, 200, 411-429.
https://doi.org/10.1016/s0378-3812(02)00048-1

has been cited by the following article:

• TITLE: Thermodynamics of Phase Transitions for Pure Substances and Mixtures

  AUTHORS: Jan Helm

  KEYWORDS: Gibbs Free Energy, Helmholtz Free Energy, Enthalpy, Equation-of-State, Phase Transition, Van-Der-Waals Equation-of-State, Peng-Robinson Equation-of-State, Mie-Grueneisen Equation-of-State, Maxwell Rule, Saturation Curve, Binary Mixture

  JOURNAL NAME: Journal of Modern Physics, Vol.17 No.5, May 27, 2026

  ABSTRACT: This paper presents in a concise way the mathematical models and experimental data of phase transitions of pure substances and solutions with new ansatz and calculation methods. In chap. 2 and chap. 3 we deal with the theoretical basics of solutions and mixtures. In chap. 4, the theory of equations-of-state is formulated, and in chap. 5 the calculation results for four pure substances (benzene, ethanol, argon, carbon dioxide) are presented and commented. In chap. 6, the equation-of-state and mixing rules for mixtures are formulated, and the calculation results for an example solution (benzene-ethanol) are discussed and compared with measured values. The paper introduces two novel methods: 1) Exact algebraic solution for phase diagrams based on Peng-Robinson and Mie-Grueneisen equation-of-state; 2) A new ansatz for mixture phase diagrams based on the weighted sum of partial pressures.