TITLE:
Comparative Efficacy of Polyamine-Based Scavenger Resins
AUTHORS:
Krishnarao Sandhya, Bhagavathula Ravindranath
KEYWORDS:
Acids; Acid Chlorides; Aldehydes; Isocyanates; Ethylenediamine; Diethylenetriamine;Triethylenetetramine; Tris(2-aminoethyl)amine; Scavenger Resins; Combinatorial Synthesis
JOURNAL NAME:
International Journal of Organic Chemistry,
Vol.2 No.1,
March
15,
2012
ABSTRACT: Polyamine-based scavenger resins containing 2, 3 and 4 nitrogen atoms have been prepared and their comparative efficacy to scavenge appropriate electrophilic chemicals (acids, acid chlorides, isocyanates and aldehydes) from solutions has been studied. As expected, the scavenging efficiency is directly proportional to the number of nucleophic nitrogens present on the resin. The results have been compared with the performance of the popular scavenger resin, namely, tris(2-aminoethyl)amine resin, to conclude that the low-cost polyamine resins now prepared can be conveniently used as effectively as the expensive commercial product.