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M. Fleischmann, K. Korinek and D. Pletcher, “The Kinetics and Mechanism of the Oxidation of Amines and Alcohols at Oxide-Covered Nickel, Silver, Copper, and Cobalt Electrodes,” Journal of the Chemical Society, Perkin Transactions, Vol. 2, No. 10, 1972, pp. 1396- 1403.

has been cited by the following article:

• TITLE: Utilization of Special Potential Scan Programs for Cyclic Voltammetric Development of Different Nickel Oxide-Hydroxide Species on Ni Based Electrodes

  AUTHORS: Diego E. Pissinis, Leónides E. Sereno, Juan M. Marioli

  KEYWORDS: Nickel; Nickel-Chromium Alloy; Oxides; Cyclic Voltammetry

  JOURNAL NAME: Open Journal of Physical Chemistry, Vol.2 No.1, February 27, 2012

  ABSTRACT: Special potential scan programs were designed for cyclic voltammetric development of β-NiOOH or γ-NiOOH/ β-NiOOH mixtures on the surface of nickel or nickel-chromium (80:20) alloy electrodes in NaOH 0.10 M. The pro- grams consisted on changing the anodic or cathodic switching limit to facilitate the chemical reactions taking place ei- ther between Ni(II) hydroxides or between Ni(III) oxides-hydroxides. The electrochemical charge density under the oxidative wave, observed at Ni or Ni-Cr electrode surfaces at approximately 0.48 V (vs SCE), remained almost con- stant with the number of cv cycles after approximately 600 cv cycles at 0.050 V/s. Thus, it can be suggested that a stable proportion of Ni(II)/Ni(III) oxides-hydroxides was obtained on the electrode surfaces. The relative amounts of β-NiOOH or γ-NiOOH species were calculated from the electrochemical charges under their reduction waves in the voltammetric experiments. Higher charge densities were always obtained with Ni-Cr alloy electrodes as compared to pure Ni electrodes. Linear relationships were obtained in our study on the dependence of the oxidative peak current with the square root of the scan rate at a scan rate range between 0.01 V/s and 0.16 V/s.