TITLE:
Process Optimization and Modeling by Response Surface Methodology of Nitrite Electro-Reduction by Ti/RuO2 + IrO2 Electrode
AUTHORS:
Mar Bassine Boye, Abdou Khadre Djily Dimé, Adama Diop, Cheikhou Kane, Modou Fall
KEYWORDS:
Electrochemical Reduction, Water Treatment, Nitrite, Optimization, Modelling
JOURNAL NAME:
American Journal of Analytical Chemistry,
Vol.14 No.12,
December
21,
2023
ABSTRACT: Electrochemical reduction is one of the most suitable methods for the treatment of highly nitrate-contaminated solutions. This work focuses on the optimization of parameters influencing the electrochemical denitrification of water by the Ti/RuO2 + IrO2 electrode. The methodological approach used consists in carrying out a series of electrolysis by scrutinizing the reaction selectivity according to the experimental conditions. For this study, theions concentrations before and after electrolysis were determined by UV-vis absorption spectroscopy. The results of the process optimization showed that the electrochemical reduction ofis efficient at neutral pH after 120 mn of electrolysis at -100 mA. In contrast to works found in the literature, this study highlighted the process modeling that could open interesting perspectives to develop new treatment methods of polluted waters.