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Periana, R.A. and Bergman, R.G. (1986) Carbon-Carbon Activation of Organic Small Ring Compounds by Arrangement of Cycloalkylhydridorhodium Complexes to Rhodacycloalkanes. Synthesis of Metallacyclobutanes, Including One with a Tertiary Metal-Carbon Bond, by Nucleophilic Addition to .pi.-allyl Complexes. Journal of American Society, 108, 7346-7355.
https://doi.org/10.1021/ja00283a033

has been cited by the following article:

• TITLE: Copper-Catalyzed C-C(O)C Bond Cleavage of Monoalkylated β-Diketone: Synthesis of α,β-Unsaturated Ketones

  AUTHORS: Tony Wheellyam Pouambeka, Victor N’goka, Narcisse Nicaise Obaya, Guy Crépin Enoua, Hubert Makomo, Qian Zhan

  KEYWORDS: Monoalkylated β-diketone, α, β-Unsaturated Ketones, Copper-Catalyzed, C-C(O)C Bond Cleavage

  JOURNAL NAME: International Journal of Organic Chemistry, Vol.13 No.2, June 13, 2023

  ABSTRACT: A new and simple route for the synthesis of α,β-unsaturated ketones via cleavage of the C-C(O)C single bond of monoalkylated β-diketone has been described. The reaction was catalyzed by copper, a cheap transition metal in a weakly basic medium (K3PO4) at room temperature. To carry out this study, we first had to synthesize the monoalkylated β-diketones 1. Afterwards, α,β-unsaturated ketones 2 were obtained with high yields around 80%. Finally, all the products were characterized by 1H NMR, 13C NMR, and HRMS spectra.