Article citationsMore>>

Zhang, J.Y., Liu, C.M., Zhang, D.Q., Gao, S. and Zhu, D.B. (2007) Syntheses, Crystal Structures, and Magnetic Properties of Two Cyclic Dimer M2L2 Complexes Constructed from a New Nitronyl Nitroxide Ligand and M(hfac)2 (M = Cu2+, Mn2+). Inorganica Chimica Acta, 360, 3553-3559.
https://doi.org/10.1016/j.ica.2007.04.026

has been cited by the following article:

• TITLE: Two Cu(II)-Nitronyl Nitroxide Complexes Including Cyclic Dimer: Synthesis, Structures and Magnetic Interactions

  AUTHORS: Jing Chen, Chenzhuo Liu, Youjuan Zhang, Qinglun Wang

  KEYWORDS: Flexible Nitronyl Nitroxide, Cu(II) Complex, Synthesis, Characterization, Magnetic Property

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.12 No.4, November 24, 2022

  ABSTRACT: Using two new flexible and functional nitronyl nitroxide radicals as ligands, twocopper (II) complexes {[Cu(hfac)2]3(NITmPhO3Py)2}n (1) and [Cu(hfac)2 (NIToPhO3Py)]2 (2) (NITmPhO3Py = 2-[(3-methoxy-pyridinyl)phen-3-yl]- 4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, NIToPhO3Py = 2-[(3-methoxy-pyridinyl)phen-2-ly]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, hfac = hexafluoroacetylacetone), have been characterized structurally and magnetically. The X-ray crystal analyses showed that complex 1 displayed a chain polymer structure which formed with {[Cu(hfac)2]3(NITmPhO3Py)2}n due to the cross-linking of two cyclic binuclear fragments {[Cu(hfac)2]2(NITmPhO3- Py)2} via the bridging unit [Cu(hfac)2]; complex 2 presented a binuclear cyclic structure [Cu(hfac)2]2(NIToPhO3Py)2. The magnetic behaviors of the two complexes 1 and 2 have been investigated. Magnetic studies showed that antiferromagnetic interactions dominated in complex 1, while there existed ferromagnetic interactions between Cu(II) and coordinated NO group in complex 2.