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Tan, S.-J., Yue, J., Tian, Y.-F., Ma, Q., Wan, J., Xiao, Y., Zhang, J., Yin, Y.-X., Wen, R. and Xin, S. (2021) In-Situ Encapsulating Flame-Retardant Phosphate into Robust Polymer Matrix for Safe and Stable Quasi-Solid-State Lithium Metal Batteries, Energy Storage. Materials, 39, 186-193.
https://doi.org/10.1016/j.ensm.2021.04.020

has been cited by the following article:

• TITLE: Zinc and Silver Salts-Containing Lamellar Titanium Phosphate: A Multifunctional Filler

  AUTHORS: Enzo Erbisti Garcia, Gerson Alberto Valencia Albitres, Daniela França Silva Freitas, Danielle Mattos Mariano, Luis Cláudio Mendes

  KEYWORDS: Titanium Phosphate, Intercalation, Pyromellitic Acid, Zinc Acetate, Silver Nitrate, Ethylamine

  JOURNAL NAME: Materials Sciences and Applications, Vol.13 No.6, June 20, 2022

  ABSTRACT: Zinc and silver compounds have been studied because they have ultraviolet light barrier properties and bactericidal action, respectively. Materials with multifunctional characteristics have been sought to produce polymeric nanocomposites. In this work, the chemical modification of titanium phosphate (TiP) was carried out through a route with successive intercalations. TiP was synthesized and consecutively pre-expanded with ethylamine and pyromellitic acid. Then it was modified with zinc acetate and silver nitrate. The final product was characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, wide-angle X-ray diffractometry, field emission scanning electron microscopy coupled with energy dispersive X-ray spectroscopy and thermogravimetry. Infrared revealed dislocation and appearance of bands according to the intercalating agent. Inorganic salts interfered in the crystallization and melting processes of pyromellitic acid. Vanishing of the TiP hkl plane and variation and appearance of new crystallographic planes at low diffraction angles induced intercalation. SEM showed agglomerated structures. New thermal degradation events at higher temperatures endorsed the formation of zinc and silver carboxylate salts. We concluded that a new miscellaneous and multifunctional matter was achieved.