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El-Damrawi, G., Hassan, A.K., Ehmead, S. and El Shahawy, A. (2017) Advantage of NMR and FTIR Spectroscopy to Determine Structure Role of CeO2 in Complicated Borosilicate Glasses: New Approach. New Journal of Glass and Ceramics, 7, 22-33.
https://doi.org/10.4236/njgc.2017.72003

has been cited by the following article:

• TITLE: Mechanism of Cluster Formation on Cerium Borosilicate Glasses Based on TEM-EDP and SEM-EDEX Investigations

  AUTHORS: Salma Ahmeed, Gomaa El Damrawi

  KEYWORDS: TEM-EDP, SEM-EDEX, Cluster Formation, Cerium Borosilicate Glasses

  JOURNAL NAME: Journal of Minerals and Materials Characterization and Engineering, Vol.10 No.2, March 17, 2022

  ABSTRACT: Cerium oxide has a great capacity to remove nonbridging oxygen atoms (NBO) from the glass network and serves as glass former units. The well formed CeO4 units played the role of decreasing NBO from the silicate network and cause a reduction in the concentration of tetrahedral boron groups (N4). The highest content of NBO in glass of lower CeO2 (1 mol%) has a dominant role in constructing crystalline clusters in the glass. Higher CeO2 concentration leads to formation of an amorphous glass network as documented by XRD and TEM-EDP spectra. Coordination of cerium with oxygen atoms gives uniform units of spherical morphology in the pure CeO2 as well as in cerium rich glass. Clustered species has a great benefit in the field of application, used as a shielding material for ionized radiations.