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Fregnan, G.B. and Torsello, A.L. (1975) Topical Anti-Inflammatory Activity of Dexamethasone 17-Valerate and Other Corticosteroids. Current Therapeutic Researc, 17, 375-381.

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• TITLE: Oxone-Mediated Preparation of Ester Derivatives Using Indium(III) Triflate and Various Alcohols

  AUTHORS: Tomoko Mineno, Daiki Takano, Saika Komiya, Azusa Sato, Hisao Kansui

  KEYWORDS: Oxone, Oxidative Esterification, Benzaldehyde Derivatives, Ester Derivatives, Indium(III) Triflate, Alcohols

  JOURNAL NAME: Green and Sustainable Chemistry, Vol.12 No.1, February 17, 2022

  ABSTRACT: Esters are known as one of the most fundamental chemical moieties and also essentially useful components, especially for medicinal agents. Herein, using benzaldehyde and its derivatives as starting materials, Oxone-mediated preparation of ester derivatives in the presence of a catalytic amount of indium(III) triflate is described. Alcohols with various chain lengths, which functioned as solvents and substrates, were examined. Overall, the oxidative esterification starting with benzaldehyde derivatives possessing electron withdrawing groups proceeded smoothly and gave sufficient yields, in comparison to the reactions with the derivatives having electron donating groups.