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Stoclet, G., Seguela, R., Lefebvre, J.M. and Rochas, C. (2010) New Insights on the Strain-Induced Mesophase of Poly(d,l-lactide): In Situ WAXS and DSC Study of the Thermo-Mechanical Stability. Macromolecules, 43, 7228-7237. https://doi.org/10.1021/ma101430c

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• TITLE: Precise Synthesis of Acrylate Copolymer via RAFT Polymerization and Its Application

  AUTHORS: Lei Li, Jinxing Song, Xin Yang, Shengpeng Wang, Zuguang Li, Yingying Chen, Aiyuan You

  KEYWORDS: RAFT Polymerization, Different Sequence Structure, Crystallization Prop-erty, Water Repellency

  JOURNAL NAME: Journal of Materials Science and Chemical Engineering, Vol.9 No.6, June 30, 2021

  ABSTRACT: A series of different sequence structure containing stearyl acrylate (SA) and hydroxyethyl acrylate (HEA) copolymer were synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization. The crystallization property of PHEA-b-PSA, PHEA-b-PSA-b-PHEA, PSA-b-PHEA-b-PSA, PHEA-co-PSA, and PHEA-grad-b-PSA were characterized by Differential Scanning Calorimetry (DSC). The condensed structure of different sequence copolymers were investigated using small-angle X-ray scattering (SAXS). A series of copolymers with different sequence structure were coated on the surface of polyester fabric, which can be found that PHEA-b-PSA-b-PHEA block copolymer has good water repellency.