TITLE:
Adsorption Isotherm, Kinetic and Thermodynamic Modelling of Bacillus subtilis ATCC13952 Mediated Adsorption of Arsenic in Groundwaters of Selected Gold Mining Communities in the Wassa West Municipality of the Western Region of Ghana
AUTHORS:
Emmanuel Agyapong Asare, Emmanuel Dartey, Kofi Sarpong, Emmanuel Effah-Yeboah, Papa Kofi Amissah-Reynolds, Sheila Tagoe, Gadafi Iddrisu Balali
KEYWORDS:
Adsorption Isotherms, Bacillus subtilis ATCC13952, Kinetic, Thermodynamic, Nonlinear Error Functions, Sum of the Normalized Errors, Chemisorption
JOURNAL NAME:
American Journal of Analytical Chemistry,
Vol.12 No.5,
May
21,
2021
ABSTRACT: This study investigated Bacillus subtilis ATCC13952 as an adsorbent for arsenic in groundwater. Batch experiments were used to determine the effect of contact time, adsorbent dose, arsenic (III) concentration, pH, and temperature on the process. The percentage of arsenic (III) removed was high at a contact time of four days, 3.0 mL of Bacillus subtilis ATCC13952, pH 8 and temperature of 35°C. The kinetics of the process showed the Elovich kinetics model as the best fit for the process. This indicates that arsenic removal was by chemisorption. The analysis of the nonlinear equilibrium isotherms and the error functions showed the Langmuir isotherm as best fit for the process. Mechanistic study of the process indicated bulk diffusion to be the rate-determining step. Thermodynamically, the process was favourable, spontaneous and feasible. When the community water samples were treated with the Bacillus subtilis ATCC13952 at the optimum contact time, adsorbent dose, pH and temperature, 99.96% - 99.97% of arsenic was removed across all sampling points within the studied communities. Hence, the results show that Bacillus subtilis ATCC13952 is an efficient adsorbent for arsenic in aqueous systems and the organism appears to hold the key to purging the environment of arsenic contamination.