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Ortiz-Landeros, J., Gómez-Yáñez, C., Palacios-Romero, L.M., Lima, E. and Pfeiffer, H. (2012) Structural and Thermochemical Chemisorption of CO₂ on Li_4+x(Si_1-xAl_x)O₄ and Li_4-x(Si_1-xV_x)O₄ Solid Solutions. Journal of Physical Chemistry A, 116, 3163-3171.
https://doi.org/10.1021/jp3006298

has been cited by the following article:

• TITLE: High Performance of Fly Ash Derived Li 4SiO4-Based Sorbents for High Temperature CO2 Capture

  AUTHORS: Shenggen Wu, Xiaoli Liang, Qi Zhang, Guiru Zhang

  KEYWORDS: Fly Ash, Lithium Orthosilicates, Molar Ratios, CO2 Capture

  JOURNAL NAME: Journal of Encapsulation and Adsorption Sciences, Vol.11 No.1, March 19, 2021

  ABSTRACT: It is urgent to develop excellent solid CO2 sorbents with higher sorption capacity, simpler synthetic process, better thermal stability and lower costs of synthesis in CO2 capture and storage technologies. In this work, a number of Li4SiO4-based sorbents synthesized by lithium carbonate with three different kinds of fly ashes in various molar ratios were developed. The results indicate that the Li2CO3:SiO2 mole ratio used in the sorbents synthesis significantly affects the CO2 absorption properties. The sorption capacity increased with the excess of Li2CO3 first and then decreased when the excessive quantity was beyond a certain amount. The experiments found that FA-Li4SiO4_0.6, CFA-Li4SiO4_0.4, HCl/CFA-Li4SiO4_0.3 presented the best sorption ability among these fly ash derived Li4SiO4 samples, and the corresponding weight gain was 28.2 wt%, 25.1 wt% and 32.5 wt%, respectively. The three sorbents with the optimal molar ratio were characterized using various morphological characterization techniques and evaluated by thermogravimetric analysis for their capacity to chemisorb CO2 at 450°C - 650°C, diluted CO2 (10%, 20%) and in presence of water vapor (12%). The adsorption curve of FA- Li4SiO4_0.6 at different temperatures was simulated with the Jander-Zhang model to explore the influence of carbon dioxide diffusion on adsorption reaction. Further experiments showed that the adsorbent had a good sorption capacity in a lower partial pressure of CO2 and the presence of steam enhanced the mobility of Li+. What’s more, FA-Li4SiO4_0.6, CFA-Li4SiO4_0.4 and HCl/CFA-Li4SiO4_0.3 particles showed satisfactory sorption capacity in fixed-bed reactor and excellent cyclic sorption stability during 10 sorption/ desorption cycles.