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Kubota, H. and Kuwabara, S. (1997) Cellulosic Absorbents for Water Synthesized by Grafting of Hydrophilic Vinyl Monomers on Carboxymethyl Cellulose. Journal of Applied Polymer Science, 64, 2259-2263.
https://doi.org/10.1002/(SICI)1097-4628(19970613)64:11%3C2259::AID-APP21%3E3.0.CO;2-Y

has been cited by the following article:

• TITLE: Emulsion Graft Polymerization of Methyl Methacrylate onto Cellulose Nanofibers

  AUTHORS: Hiromu Okada, Chao Zhao, Yusuke Mizuta, Katsumi Yoshino, Ryuichi Sugimoto

  KEYWORDS: Cellulose Nanofibers, Graft Polymerization, Methyl Methacrylate, Emulsion, Diethylzinc

  JOURNAL NAME: Green and Sustainable Chemistry, Vol.11 No.1, February 4, 2021

  ABSTRACT: Methyl methacrylate (MMA) was successfully grafted onto cellulose nanofibers (CNFs) at room temperature in an emulsion system using a diethyl(1,10-phenanthroline N1,N10)zinc(II) complex (Phen-DEZ) with oxygen as the radical initiator. The effects of reaction temperature, initiator concentration, and monomer content on the grafting reaction were investigated. The molecular weight of the non-grafted PMMA, which was produced during graft polymerization, was more than 1 million, as determined by size exclusion chromatography. The PMMA-grafted CNFs were analyzed by Fourier transform infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy, which confirmed the grafting of PMMA on the nanofiber surface. The study presents a strategy for the grafting of high-molecular weight PMMA onto CNFs in an emulsion system using Phen-DEZ and O2.