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Wang, Y., Xing, P., Lin, S., Ma, M., Yang, M., Zhang, Y., Wang, B. and Hao, A. (2016) Facile Stimuli-Responsive Transformation of Vesicle to Nanofiber to Supramolecular Gel via ω-Amino Acid-Based Dynamic Covalent Chemistry. Langmuir, 32, 10705-10711. https://doi.org/10.1021/acs.langmuir.6b02478
has been cited by the following article:
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TITLE:
Fluoride-Responsive Organogel Based on Hydrazide Derivatives
AUTHORS:
Guanghui Lv, Lirong Lin, Xinyang Chen, Chaoran Chen, Lei Huang, Hong Xin
KEYWORDS:
Organogel, Hydrazine Derivatives, Fluoride Response, Hydrogen Bonding
JOURNAL NAME:
Journal of Materials Science and Chemical Engineering,
Vol.8 No.12,
December
21,
2020
ABSTRACT: An organogelator named N-[3-(hydroxy)-4-(dodecyloxy)-benzoyl]-N’ (4’-nitro-benzoyl) hydrazide (D12) was synthesized. It could form stable gels in some of the tested organic solvent. SEM images revealed that the molecules self- assembled into fibrous aggregates in the xerogels. The X-ray diffraction analysis showed that the xerogel exhibited a layered structure. FT-IR studies confirmed that intermolecular hydrogen bonding between C=O and N-H groups was the major driving force for gelation of organic solvents. The gel exhibited gel-sol transition and color change upon addition of F-. An extended conjugated system formed through the phenyl group and a five-membered ring based on intramolecular hydro-gen bonding between the oxygen atom near the deprotonation nitrogen atom and the other NH, which is responsible for the dramatic color change upon addition of F-.