Article citationsMore>>

A. H. Naik, S. S. Deb, A. B. Chalke, M. K. Saxena, K. L. Ramakumar, V. Venugopal and S. R. Dharwadkar, “Microwave-Assisted Low Temperature Synthesis of So- dium Zirconium Phosphate (NZP) and the Leachability of Some Selected Fission Products Incorporated in Its Struc- ture―A Case Study of Leachability of Caesium,” Journal of Chemical Science, Vol. 122, No. 1, 2010, pp. 71-82. doi:10.1007/s12039-010-0009-8

has been cited by the following article:

• TITLE: Electrical and Dielectric Characterization of Na0.5Li0.5Zr2(PO4)3

  AUTHORS: Umaru Ahmadu, Kasim Uthman Isah, Abubakar Ohinoyi Musa, Tomas Salkus

  KEYWORDS: NZP, Impedance Spectroscopy, Dielectric Relaxation, Electrical Conductivity

  JOURNAL NAME: Open Journal of Physical Chemistry, Vol.1 No.3, November 25, 2011

  ABSTRACT: Na0.5Li0.5Zr2(PO4)3has been synthesized by solid state reaction and characterized by thermogravimetry/ differential thermal analyses (TGA/DTA) in the temperature range 300 - 1573 K. X-ray diffraction measure- ments have been carried out to determine the phase of the composition and scanning electron microscopy (SEM) for microstructure evaluation. Impedance spectroscopy at different temperatures (310 - 600 K) and frequencies (300 kHz - 1 GHz) have been carried out and the dielectric relaxation behaviour was determined under the same conditions. A dc conductivity maximum value of 0.25 S/m at 580 K was observed. However, the mixed alkali effect was not observed. The material exhibited relaxation behaviour with a peak in the dielectric permitivity at 469 K. There were no structural transformations observed.