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Kim, J., Jeerapan, I., Sempionatto, J.R., Barfidokht, A., Mishra, R.K., Campbell, A.S., Hubble, L.J. and Wang, J. (2018) Wearable Bioelectronics: Enzyme-Based Body-Worn Electronic Devices. Accounts of Chemical Research, 51, 2820-2828.
https://doi.org/10.1021/acs.accounts.8b00451

has been cited by the following article:

• TITLE: A Glucose-Responsive Enzymatic Electrode on Carbon Nanodots for Glucose Biosensor and Glucose/Air Biofuel Cell

  AUTHORS: Yue Gao, Guozhi Wu, Feng Gao

  KEYWORDS: Carbon Nanodots, Glucose Dehydrogenase, Laccase, Methylene Green, Biosensor, Biofuel Cell

  JOURNAL NAME: American Journal of Analytical Chemistry, Vol.10 No.9, September 18, 2019

  ABSTRACT: In this study, an enzymatic electrode for glucose biosensing and bioanode of glucose/air biofuel cell has been fabricated by immobilizing poly (methylene green) (polyMG) for electrocatalytic NADH oxidation and NAD+-dependent glucose dehydrogenase (GDH) for oxidizing glucose on carbon nanodots (CNDs). The polyMG-CNDscomposites obtained by electro-polymerization of dye MG molecules adsorbed on CNDs display excellent electrocatalytic activity toward NADH electro-oxidation at a low overpotential of ca. -0.10 V (vs. Ag/AgCl) and the integrated enzymatic electrode shows fast response to glucose electrooxidation. Using the fabricated GDH-based enzymatic electrode, a glucose biosensor was constructed and exhibits a wide linear dynamic range from 0 to 8 mM, a low detection limit of 0.02 μM (S/N = 3), and fast response time (ca. 4 s) under the optimized conditions. The developed glucose biosensor was used to detect glucose content in human blood with satisfactory results. The fabricated GDH-based enzymatic electrode was also employed as bioanode to assembly a glucose/air biofuel cell with the laccase-CNDs/GC as the biocathode. The maximum power density delivered by the assembled glucose/air biofuel cell reaches 3.1 μW·cm-2 at a cell voltage of 0.22 V in real sample fruit juice. The present study demonstrates that potential applications of GDH-based CNDs electrode in analytical and biomedical measurements.