Article citationsMore>>

Wu, D.S., Cheng, W.D., Li, X.D., Lan, Y.Z., Chen, D.G., Zhang, Y., Zhang, H. and Gong, Y.J. (2004) First Principles Treatment of Configuration Optimizations, Excited-State Properties, and Dynamic Third-Order Polarizabilities of Chloro-Metal Phthalocyanines MPcCl (M = Al, Ga, In). The Journal of Physical Chemistry A, 108, 1837-1843.
https://doi.org/10.1021/jp0365211

has been cited by the following article:

• TITLE: Structural Characterizations for Glass Ionomer Cement Doped with Transition Metal Phthalocyanines

  AUTHORS: Gomaa El Damrawi, Amal Behairy, Riham Atef

  KEYWORDS: Cerium Phosphate, Metal Phthalocyanine, Bundles Phases, 31P NMR Spectros-copy

  JOURNAL NAME: New Journal of Glass and Ceramics, Vol.9 No.4, September 18, 2019

  ABSTRACT: Glass and Glass iomomer cement (GICs) based on a specific composition of cerium phosphate glass (40 CeO2-60P2O5) have been prepared. Effect of the doping type at a fixed doping concentration from metal-phthalocyanines (M-PCs) on material structure and morphologies has been carefully studied. The corresponding changes in the material structure were widely followed up by31P MAS NMR, X-Ray diffraction and FTIR spectroscopy. The network structure of both base glass and GIC which all free from metal phthalocyanines has been confirmed to be amorphous. GIC doped with M-PCs has shown a more ordered structure. There were clear changes in the position and intensities of31P NMR spectral peaks of glasses upon changing the dopant type. In all cases, a little concentration from M-Phthalocyanine (0.8 mol%) leads to changing the network structure from amorphous to a more ordered structure. Phosphate structural phases are evidenced to be formed upon addition of a fixed amount of M-PCs (Ga, Co, Fe). The morphologies of some selected samples were characterized by SEM. The micrographs have revealed that formulating of cerium phosphate powder of the amorphous glass with a polymeric acid successfully led to the formation of CePO4-H2O bundles phases. But formulation with GIC containing Co or Fe or Ga Phthalocyanine can simply form co-aligned linear slaps and elongated nanofibers which are consisted of hydrated and carbonated CePO4a GaPO4, FePO4or CoPO4crystals. The structure of all doped materials has a lower crack length than that of base glass. This was discussed on bases of formation of more aligned and elongated tough-fibers in matrix of all doped materials. Such tough fibers have ability to withstand breaking stress via suppressing crack propagation.