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DeCoste, J.B., Peterson, G.W., Schindler, B.J., Killops, K.L., Browe, M.A. and Mahle, J.J. (2013) The Effect of Water Adsorption on the Structure of the Carboxylate Containing Metal-Organic Frameworks Cu-BTC, Mg-MOF-74, and UiO-66. Journal of Materials Chemistry A, 1, 11922-11932.
https://doi.org/10.1039/c3ta12497e

has been cited by the following article:

• TITLE: Forward Looking Analysis Approach to Assess Copper Acetate Thermal Decomposition Reaction Mechanism

  AUTHORS: Itab Youssef, Sécou Sall, Thierry Dintzer, Sana Labidi, Corinne Petit

  KEYWORDS: In-Operando Spectroscopy and Chromatography, Thermal Decomposition Reaction Mechanism, Copper Acetate, Cross-Linked Characterization Data

  JOURNAL NAME: American Journal of Analytical Chemistry, Vol.10 No.5, May 10, 2019

  ABSTRACT: Thermal decomposition course of copper acetate monohydrate was monitored by combining diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) coupled with μ gas chromatography-mass spectrometry (μGC-MS) with other analytical techniques (thermogravimetry analysis and in situ X-ray diffraction). Non-isothermal kinetic was examined in air and Ar. A complete analysis of the evolution of infrared spectra matched with crystalline phase transition data during the course of reaction allows access to significant and accurate information about molecular dynamics. While thermogravimetry gives broad conclusion about two steps reaction (dehydration and decarboxylation), in line approach (in situ X-ray and in situ DRIFT coupled to μGC-MS) is proposed as an example of a new robust and forward-looking analysis. While decomposition mechanism of copper acetate monohydrate is still not well elucidated yet previously, the present in-line characterization results lead to accurate data making the corresponding mechanism explicit.