TITLE:
Efficient Removal of Reactive Orange 107 Dye from Aqueous Media by Shrimp Shell Derived Chitosan Functionalized Magnetic Nanoparticles
AUTHORS:
Tehreem Saba, Fozia Minhas, Muhammad Imran Malik, Farah Naz Talpur, Abdul Jabbar, Muhammad Iqbal Bhanger
KEYWORDS:
Magnetic Nanoparticles, Adsorption, Chitosan Functionalization, Anionic Dyes
JOURNAL NAME:
American Journal of Analytical Chemistry,
Vol.9 No.12,
December
28,
2018
ABSTRACT: In present work chitosan functionalized magnetic nanoparticles (CMNPs) were successfully prepared and investigated for the removal of Reactive Orange 107 dye (RO 107) from water. The chitosan was extracted from shrimp shells (Penaeus merguiensis) and was characterized by solubility test and fourier transform infrared spectroscopy (FTIR). Degree of deacetylation of chitosan was examined by 1H-NMR and potentiometric titration method. Thereafter, the chitosan was used for synthesis of CMNPs. The synthesized CMNPs were characterized by FTIR, scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), thermal gravimetric analysis (TGA) and atomic force microscopy (AFM). Effects of various variables such as contact time, pH, stirring speed, adsorbent dosage, temperature, and concentration of electrolyte on extraction efficiency were evaluated. Freundlich isotherm model fits better that shows the removal of RO 107 with CMNPs by multilayer adsorption behaviour. Furthermore, kinetic study showed that adsorption process followed pseudo-second order kinetic model regulated by chemisorption. Thermodynamic analysis explained that adsorption of RO 107 onto CMNPs was endothermic as well as spontaneous. The developed CNMPs were applied to environmental remediation of spiked RO 107 treated waste water samples with 96.20% removal potential, hence, offered an effective sorbent for removal of RO 107 contaminated water samples.