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Tagirov, B.R. and Korjinskiy, M.A. (2001) Speciation of Fe(II) in H2O-HCl-(CO2) Fluid at 500-600°C and a Pressure of 2 kbar. Geochemistry, 9, 857-863.

has been cited by the following article:

• TITLE: The Chemical Mechanism of the Formation of Fluorite-Barite-Siderite Carbonatite in Karasug Fe-F-Ba-Sr-REE Deposit

  AUTHORS: Alexander V. Bolonin

  KEYWORDS: Ferrocarbonatite Ionic Melt, Chemical Reactions

  JOURNAL NAME: Open Journal of Geology, Vol.8 No.4, April 13, 2018

  ABSTRACT: Intrusive fluorite-barite-siderite carbonatite of Karasug deposit (Tuva) crystallized from ionic salt melt is dominated by iron chloride with the participation of alkali metal salts. Melt composition and main reaction of mineral formation: NaFeCl3 + 4KF + 2Na2Ca(CO3)2 + Na2Ba(CO3)2 + Na2SO4 = 6FeCO3 + 2CaF2 + BaSO4 + 14NaCl + 4KCl. The highest temperature (550°C - 650°C) brine-melt inclusions in minerals are pseudo-primary. Their predominant Na-K-chloride composition does not correspond to the primary melt, but is close to the residual brine-melt.