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Salmón, M., Zavala, N., Martínez, M., Miranda, R., Cruz, R., Cárdenas, J., Gavino, R. and Cabrera, A. (1994) Cyclic And Linear Oligomerization Reaction of 3,4,5-Trimethoxybenzyl Alcohol with A Bentonite-Clay. Tetrahedron Letters, 35, 5797-5800.
https://doi.org/10.1016/S0040-4039(00)78187-1
has been cited by the following article:
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TITLE:
Liquid Etherification of Alkoxybenzyl Alcohols, Cinnamyl Alcohols and Fluorinated Phenylalkenols with Platinum on Carbon (Pt/C) and Palladium on Carbon (Pd/C)
AUTHORS:
Thies Thiemann
KEYWORDS:
Benzyl Alcohols, Etherification, Platinum on Carbon, Palladium on Carbon, Activated Carbon, Solvent Free Reaction
JOURNAL NAME:
International Journal of Organic Chemistry,
Vol.8 No.1,
March
6,
2018
ABSTRACT: In the presence of either Pd/C or Pt/C, 4-alkoxybenzyl alcohols, 4-alkoxy-phenylalkyl alcohols and cinnamyl alcohols undergo liquid etherification to bis(4-alkoxybenzyl) ethers, bis[(4-alkoxybenzyl)alkyl] ethers and bis(cin-namyl) ethers at temperatures of 100°C - 135°C. In a number of cases, Pt/C and Pd/C as catalysts, also when they are doped with Ru, show distinct differences when the reactions run in air, with an oxidative dehydrogenation of the alcohols as side-reaction, yielding the corresponding ketones and aldehydes as by-products. Also, the reactivity of fluorinated phenylalkenols under these conditions has been investigated. Furthermore, the immobilization of alkyl aryl ethers on silica within a column with passage of hexane as solvent was found to lead to the formation and elution of styrenes from the column in fair yield.