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Bunting, H.E., Green, M.L.H., Marder, S.R., Bloor, D., Kolinsky, P.V. and Jones, R.J. (1992) The Synthesis of Ferrocenyl Compounds with Second-Order Optical Non-Linearities. Polyhedron, 11, 1489-1499.

has been cited by the following article:

• TITLE: Synthesis and Spectroscopic Properties of Ferrocenyl Derivative Containing Donor and Acceptor Groups

  AUTHORS: Makoto Minato, Chiharu Sorai, Takashi Ito, Masashi Kiguchi, Midori Kato

  KEYWORDS: Nonlinear Optical Material, Ferrocenyl Derivative, Solvatochromic Property, SHG Efficiency

  JOURNAL NAME: International Journal of Organic Chemistry, Vol.7 No.3, September 7, 2017

  ABSTRACT: Much interest has been devoted to organometallic NLO materials. We have become interested in exploring the utility of ferrocenyl group as the conjugating bridge. Thus, we synthesized 1-{{[1,3-(5-methylbenzo)dithiol]-2-yli- dene}methyl}-1’-[2-(p-nitrophenyl)-(E)-ethenyl]ferrocene (1). This new ferrocenyl compound has a donor and an acceptor group in 1,1’-positions. Investigations of the solvatochromic property of the compound revealed that it has polarized structure in a polar solvent, such as DMF. SHG efficiency of the compound was estimated by an SHEW (second-harmonic generation with the evanescent wave) method.