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El Khaldy, A.A.S., Okafor, F. and Abu Shanab, A.M. (2014) Synthesis, Spectraland Antimicrobial Studies of Bis (Cyclopentadienyl) Titanium (IV) Bis (O,O’-Dialkyl and Alkylenedithiophosphate) Complexes. International Journal of Organic Chemistry, 4, 339-346. https://doi.org/10.4236/ijoc.2014.45037

has been cited by the following article:

• TITLE: Synthesis and Spectroscopic Characterization of Eight Chloro Cyclopentadienyl Titanium Bis (O, O-Dialkyl and Alkylene Dithiophosphate) Compounds

  AUTHORS: Adnan A. S. El Khaldy, Alaa M. Abu Shanab, Yannic Boni

  KEYWORDS: Chloro Cyclopentadienyl Titanium (IV) Bis Dialkyl, Alkylene Dithiophos-phate

  JOURNAL NAME: International Journal of Organic Chemistry, Vol.7 No.2, June 12, 2017

  ABSTRACT: A series of new complexes, CpTiCl[S2P(OR)2]2 (where R) Et, n-Pr, i-Pr, Bui, Ph) and CpTiCl [S2POGO]2 (where G) –CH2CMe2CH2-, -CMe2CMe2-) have been prepared by the drop wise addition of the appropriate O, O’-dialkyl or -alkylene dithiophosphoric acid to cyclopentadienyl titanium trichloride in 1:2 molar ratio and refluxed in benzene solution. The new compounds were characterized by molecular weight measurements elemental analyses and spectroscopic studies (1H, 13C, and 31P NMR, and in-frared). We suggest a distorted tetrahedron structure of these new complexes and the dithioligand behaves as bidentate ligand.