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Jiang, L., Saldana-Greco, D., Schick, J.T. and Rappe, A.M. (2014) Enhanced Charge Ordering Transition in Doped CaFeO3 through Steric Templating. Physical Review B, 89, Article ID: 235106.
https://doi.org/10.1103/PhysRevB.89.235106

has been cited by the following article:

• TITLE: Enhancement of Oxygen Evolution Activity of Ruddlesden-Popper-Type Strontium Ferrite by Stabilizing Fe4+

  AUTHORS: Toshihiro Takashima, Koki Ishikawa, Hiroshi Irie

  KEYWORDS: Oxygen Evolution, Charge Disproportionation, Water-Splitting, Sr3Fe2O7

  JOURNAL NAME: Journal of Materials Science and Chemical Engineering, Vol.5 No.4, April 30, 2017

  ABSTRACT: Development of active iron based water oxidation for designing an ideal artificial photosynthesis devices operating under benign neutral pH is highly demanded. We investigated the electrocatalytic activity of Ruddlesden-Pop-per-type strontium ferrite (Sr3Fe2O7) toward the oxygen evolution reaction (OER). Owing to the temperature-dependent efficiency of the charge disproportionation of Fe4+, the OER activity of Sr3Fe2O7 varied with the temperature, and the onset potential for the OER at a neutral pH underwent a negative shift of approximately 200 mV by increasing the temperature for the stabilization of Fe4+. When metal substitution was made to Sr3Fe2O7 for stabilizing Fe4+ at room temperature, the temperature dependence of the OER activity disappeared and the OER was driven at a small overpotential without increasing the temperature, indicating that the stabilization of Fe4+ is substantially important for achieving high OER activity.