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Wu, C., Wu, F., Bai, Y., Yi, B. and Zhang, H. (2005) Cobalt Boride Catalysts for Hydrogen Generation from Alkaline NaBH4 Solution. Materials Letters, 59, 1748-1751.

has been cited by the following article:

• TITLE: Hydrogen Generation by Reforming of Sodium Hypophosphite on Cobalt-Boron Oxides Containing Catalyst

  AUTHORS: Paata Nikoleishvili, Giorgi Gorelishvili, Valentina Kveselava, Gigla Tsurtsumia, Nikoloz Nioradze, Rusudan Kurtanidze, Dali Dzanashvili

  KEYWORDS: Cobalt-Boron Oxide, Hydrogen, Catalyst, Reforming, Sodium Hypophosphite

  JOURNAL NAME: Green and Sustainable Chemistry, Vol.7 No.1, February 28, 2017

  ABSTRACT: Cobalt-Boron oxides containing catalyst CoO·B2O3 (CoB2O4) are synthesized for hydrogen generation by catalytic reforming of basic solution of sodium hypophosphite (NaH2PO2) and identified by chemical and X-ray analysis. Reforming is performed in temperature range of 30°C - 80°C. Reaction rate constants at each value of temperature (k30°C = 8.53 × 10?4 s?1; k40°C = 1.62 × 10?4 s??; k50°C = 3.06 × 10?3 s?1; k60°C = 5.06 × 10?3 s?1; k80°C = 1.39 × 10?2 s?1), temperature coefficient of rate of chemical reaction (γ = 0.917) and activation energy (EA = 49.59 kJ·mol?1) are calculated.