Article citationsMore>>

Moriguchi, T., Egami, T., Yakeya, D., Jalli, V., Yoza, K. and Tsuge, A. (2016) Synthesis and Crystal Structure Determination of 4’,9’,4”,9”-Tetra-t-Butyl-1’, 6’,1”,6”-Tetramethoxy-2,5-Dithia[3.3] Metabiphenylophane. Crystal Structure Theory and Applications, 5, 56-62.
https://doi.org/10.4236/csta.2016.53005

has been cited by the following article:

• TITLE: Synthesis and Molecular Structures of Two Novel π-Conjugation Extended Dithia[3.3]metacyclophanes

  AUTHORS: Tetsuji Moriguchi, Daisuke Yakeya, Venkataprasad Jalli, Akihiko Tsuge, Kenji Yoza

  KEYWORDS: Cyclophane, X-Ray Analysis, Suzuki Coupling, π-Conjugation

  JOURNAL NAME: Crystal Structure Theory and Applications, Vol.6 No.1, February 17, 2017

  ABSTRACT: Two novel dithia[3.3]metacyclophanes substituted with ethynyl groups were synthesized as small-sized metacyclophanes from the corresponding brominated dithia-metacyclophanes via C-C bond formation reaction. These compounds were characterized by using 1H NMR, mass spectrometry and elemental analyses. The exact structures were determined by using X-ray diffraction analyses. X-ray diffraction analysis results revealed that these compounds have anti conformations because of existence of intermolecular π-π interaction and some short contacts in the crystal. The long wavelength fluorescence was observed for one of the compound having a pyrene moiety in solid state because of the existence of the intermolecular π-π interaction between two pyrene units.