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Goodgame D.M.L. and Goodgame, M. (1965) Near-in- frared spectra of some pseudotetrahedral complexes of cobalt(II) and nickel(II). Inorganic Chemistry, 4, 139-143. doi:10.1021/ic50024a002

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• TITLE: Thermochemical parameters of 1,2,3,4-tetrahydroquinoline adducts of some divalent transition metal bromides

  AUTHORS: Pedro O. Dunstan

  KEYWORDS: Transition Metal Complexes; Thermochemistry; Coordinated Bonds Energies; Dissolution Enthalpies; Calorimetry

  JOURNAL NAME: Natural Science, Vol.3 No.7, July 29, 2011

  ABSTRACT: The adducts [MBr2(L)n], where M = Fe, Co, Ni, Cu or Zn; L = 1,2,3,4-tetrahydroquinoline (THQ); n = 0.75, 1 or 2 have been obtained from the interaction in hot solution of THQ with the metal(II) bromides. The compounds were characterized by melting points, elemental analysis, thermal analysis and IR spectroscopy. From calorimetric studies in solution, the standard enthalpies of formation of them and several other thermochemical parameters were determined. The mean standard enthalpies of the metal(II)-nitrogen bonds have been estimated.