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• TITLE: Spectroscopic investigation and density functional theory calculations of mercaptobenzothiazole and mercaptobenzimidazole ligands and their rhenium complexes

  AUTHORS: Noura AlHokbany, Ibrahim AlJammaz

  KEYWORDS: [ReO]3+, DFT, Mercaptobenzothiazole Ligand, Mercaptobenzimidazol Ligand, TG/DTA, XPS, Rhe-nium Complexes.

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.1 No.2, July 29, 2011

  ABSTRACT: Four complexes containing the [Re(V)O]3+ core have been prepared by substitution on the precursors RO(citrate)2- and ReO(gluconate)2-. The complex [ReO(MBT)2OH] was obtained by reaction of the direct reduction of ReO4- using sodium borohydride as a reducing agent. Four complexes were character-ized by UV-Vis and IR spectrophotometer, elemental analyses, 1H-and 13C NMR spectroscopy, TG and DFT calculations.