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Hasanov, H.I. (2003) Synthesis, Structure and Properties of Coordination Compounds of Platinum(II) and Palladium(II) with a Biologically Active Ligands. Doctoral Thesis, Baku.

has been cited by the following article:

• TITLE: Hexanuclear Complex of Platinum(II) with Cleavage Product of Cystamine Dihydrochloride by β-Mercaptoethylamine

  AUTHORS: Asmat N. Azizova, Dilqam B. Tagiyev, Shmid G. Gasimov, Khudayar I. Gasanov

  KEYWORDS: Mercaptoamine, Ligands, Platinum, Six-Nuclear Complexes, Synthesis

  JOURNAL NAME: Advances in Chemical Engineering and Science, Vol.6 No.1, January 12, 2016

  ABSTRACT: Six-nuclear complexes of Platinum(II) with cleavage of a cystamine dihydrochloride by β-mercaptoethylamine with composition [Pt6(H2NCH2CH2S)8]Cl4·5H2O had been syntesized for the first time. Structure of the complex had been installed together with IKS- and XRD analysis. It has been established that each atom of platinum is surrounded by two atoms of sulfur and nitrogen due to bidentate coordination of a ligand. Only two of the six platinum atoms are on the same plane; other four atoms are in the different crossing planes. Four platinum atoms form adurable metal chelate cycles, which collapse over temperature 260℃. The results of IR spectroscopy confirmed with the RS-analysis.