Article citationsMore>>
Xia, H.J., Yan, H., Shen, C., Shen, F.Y. and Zhang, P.F. (2011) Syn-thesis of Novel Carbohydrate-Based Chiral P, N Ligands and Their Applications in Cu-Catalyzed Enantioselective 1, 4-Conjugate Additions. Catalysis Communications, 16, 155-158. http://dx.doi.org/10.1016/j.catcom.2011.09.021
has been cited by the following article:
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TITLE:
Carbohydrate-Derived Organocatalysts for the Reduction of Imines with Trichlorosilane
AUTHORS:
Xin Ge, Chao Qian, Xinzhi Chen
KEYWORDS:
Carbohydrate, Organocatalyst, Reduction, Imine
JOURNAL NAME:
Journal of Materials Science and Chemical Engineering,
Vol.3 No.6,
June
12,
2015
ABSTRACT: The backbone of D-glucosamine hydrochloride
was fine-tuned and modified by protecting the hydroxyl groups. In order to
reduce imines with trichlorosilane, the carbohydrate-derived organocatalysts
were prepared and screened. Methyl-4,6-O-benzylidene-2-amino-2-deoxy-α-D-glucopyr
anoside was found as the best catalyst. The reduction was proceeded under CHCl3
as solvent at 40?C, affording 68% - 94% yield.