Article citationsMore>>
Liu, K., Cui, H.F., Nie, J., Dong, K.Y., Li, X.J. and Ma, J.A. (2007) Highly Enantioselective Michael Addition of Aromatic Ketones to Nitroolefins Promoted by Chiral Bifunctional Primary Amine-Thiourea Catalysts Based on Saccharides. Organic Letters, 9, 923-925. http://dx.doi.org/10.1021/ol0701666
has been cited by the following article:
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TITLE:
Carbohydrate-Derived Organocatalysts for the Reduction of Imines with Trichlorosilane
AUTHORS:
Xin Ge, Chao Qian, Xinzhi Chen
KEYWORDS:
Carbohydrate, Organocatalyst, Reduction, Imine
JOURNAL NAME:
Journal of Materials Science and Chemical Engineering,
Vol.3 No.6,
June
12,
2015
ABSTRACT: The backbone of D-glucosamine hydrochloride
was fine-tuned and modified by protecting the hydroxyl groups. In order to
reduce imines with trichlorosilane, the carbohydrate-derived organocatalysts
were prepared and screened. Methyl-4,6-O-benzylidene-2-amino-2-deoxy-α-D-glucopyr
anoside was found as the best catalyst. The reduction was proceeded under CHCl3
as solvent at 40?C, affording 68% - 94% yield.