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Kimura, H., Kimura, A., Kokubo, I., Wakisaka, T. and Mitsuda, Y. (1993) Palladium Based Multi-Component Catalytic Systems for the Alcohol to Carboxylate Oxidation Reaction. Applied Catalysis A: General, 95,143-169.

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• TITLE: Green and Efficient Oxidation of Octanol by Iron Oxide Nanoparticles Supported on Activated Carbon

  AUTHORS: Mohammad Sadiq, Razia Aman, Saddam Hussain, Muhammad Abid Zia, Najeeb Ur Rahman, Mohammad Saeed

  KEYWORDS: Liquid Phase, Oxidation, Dehydration, Octanol

  JOURNAL NAME: Modern Research in Catalysis, Vol.4 No.1, January 9, 2015

  ABSTRACT: Iron oxide nanoparticles were synthesized by precipitation method and supported on activated carbon. The catalyst thus obtained was characterized by various physicochemical techniques, and used for the liquid phase dehydrogenation/oxidation of octanol in a batch reactor at various temperatures in the range 30 °C - 60 °C. Maximum conversion of octanol to octanal was attained at 60°C in 30 min. However, with longer reaction time, the selectivity of the catalyst was found to change in favor of octene as a product. The catalyst could be recovered and reused multiple times without any decline in its catalytic performance.