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Toma, H.E. and Sernaglia, R.L. (1993) Equilibria and Spectroelectrochemical Studies on the Formation of Multibridged Tris(bipyrazine) Ruthenium(II) Complexes with Ruthenium-Edta Groups. Talanta, 40, 515-520.

has been cited by the following article:

• TITLE: Spectrophotometric Characterization of the Complex Generated in Solution for the Reaction of H[Ru(III)Cl2(H2EDTA)] Complex with AETS Modifier Agent

  AUTHORS: Angélica M. Lazarin, Rosana Lázara Sernaglia

  KEYWORDS: [3-(2-Aminoethyl)aminopropyl]trimethoxysilane, H[Ru(III)Cl2(H2EDTA)] Complex, Spectrophotometric Method, Molar Absorptivity

  JOURNAL NAME: Open Journal of Synthesis Theory and Applications, Vol.3 No.4, October 22, 2014

  ABSTRACT: Spectrophotometric method was used to evaluate the kinetic of the complex formation from the reaction between H[Ru(III)Cl2(H2EDTA)] and the modifier agent [3-(2-aminoethyl)aminopropyl] trimethoxysilane (AEATS) (μ = 0.50 mol.dm-3 with NaCF3COO, 298.15 K), in pseudo-first order conditions. These studies showed that the reactions are successives producing several species influenced by the concentrations ratio. The electronics spectrum of all solutions showed a band in 457 nm with variable molar absorptivity (ε).