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F. Renner, A. Stierle, H. Dosch, D. M. Kolb, T. L. Lee and J. Zegenhagen, “Initial Corrosion Observed on the Atomic Scale,” Nature, Vol. 439, No. 9, February 2006, pp. 707-710. doi:10.1038/nature04465

has been cited by the following article:

• TITLE: Electrochemical Behavior of Nanocrystalline Fe88Si12 Alloy in 3.5% NaCl Solution

  AUTHORS: Licai Fu, Jun Yang, Qinling Bi, Weimin Liu

  KEYWORDS: Fe88Si12 Alloy, Nanocrystalline, Microstructure, Electrochemical Behavior

  JOURNAL NAME: Materials Sciences and Applications, Vol.2 No.5, May 23, 2011

  ABSTRACT: Influence of microstructure on electrochemical behavior of nanocrystalline Fe88Si12 alloy has been investigated in 3.5 wt% NaCl solution. The results show that FFe88Si12 alloy with optimal corrosion resistance is composite of ordered Fe3Si and disordered Fe(Si) phases and grain size of 40 nm. Because the ordered Fe3Si structure is beneficial to form SiO2 film, which possesses good corrosion resistance compared with the Fe2O3 film from disordered Fe(Si). Moreover, although the decreased grain size is conducive to form preservative, as the grain size decreases to 10 nm, the grain boundary increases to above 30 vol%, which is the active sites for corrosion attack.