TITLE:
Impact of Vibration Models on Heat Capacities of HF Molecular System
AUTHORS:
Guo Yue Liu, Ying Wu, Bi Tao Liao
KEYWORDS:
Impact of Vibration Models on Heat Capacities of HF Molecular System
JOURNAL NAME:
Journal of Power and Energy Engineering,
Vol.2 No.9,
September
12,
2014
ABSTRACT: Based on the analysis of completeness and
finiteness of HF molecular vibrational levels, HF systemic vibrational heat
capacity is studied with quantum statistical and full set of vibrational energy
level determined AM (algebraic method). The results show that correct
vibrational description and vibrational energy level set of HF system are key
factors in calculating heat capacity, HF heat capacity data determined by AM
energy spectra {Eυ} are much superior to the ones of harmonic oscillator model,
AM results are agreement with experiment data.