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Subashini, A., Kumaravel, R., Leela, S., Stoeckli-Evans, H., Sastikumar, D. and Ramamurthi, K. (2011) Synthesis, Growth and Characterization of 4-Bromo-4-Chlorobenzylidene Aniline—A Novel Third Order Nonlinear Optical Material. Spectrochimica Acta Part A, 78, 935-941.
http://dx.doi.org/10.1016/j.saa.2010.11.041
has been cited by the following article:
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TITLE:
Synthesis, Growth and Characterization of Organic Nonlinear Optical Single Crystals of 4-Bromo-4’-Methyl Benzylidene Aniline
AUTHORS:
L. Jothi, R. Ramesh Babu, K. Ramamurthi
KEYWORDS:
Nonlinear Optical Material, Organic Compounds, Crystal Growth, Thermogravimetric Analysis
JOURNAL NAME:
Journal of Minerals and Materials Characterization and Engineering,
Vol.2 No.4,
July
24,
2014
ABSTRACT: Organic nonlinear optical material of 4-bromo-4’-methyl benzylidene aniline (BMBA) was synthesized and single crystal of BMBA was grown by solvent evaporation method at room temperature using ethanol as solvent. The crystalline nature of the grown crystals was confirmed using powder X-ray diffraction studies. The crystals were also characterized by single crystal X-ray diffraction method and their lattice parameters were determined. Thermal properties of BMBA were evaluated with thermogravimetric, differential thermal and differential scanning calorimetric analyses. Fourier transform infrared and FT-Raman spectral studies were carried out on the BMBA material to confirm the synthesized compound. 1H and 13C-nuclear magnetic resonance spectral studies were recorded to elucidate the structure of the grown crystals. Fluorescence spectrum recorded shows a peak at 485 nm. UV-Vis-NIR spectral analysis shows transmittance of ~92% in the visible region. The mechanical stability was analyzed by Vickers microhardness tester and the work hardening coefficient of the grown crystal was calculated. Second harmonic generation efficiency of the grown crystal measured by Kurtz powder technique is ~1.8 times that of potassium dihydrogen orthophosphate.