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T. Michinobu, T. Nakanishi, J. P. Hill, M. Funahashi and K. Ariga, “Room Temperature Liquid Fullerenes: An Uncommon Morphology of C60 Derivatives,” Journal of the American Chemical Society, Vol. 128, No. 32, 2006, pp. 10384-10385. doi:10.1021/ja063866z

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• TITLE: The Synthesis of Solvent-Free TiO2 Nanofluids through Surface Modification

  AUTHORS: P. Y. Yu, Y. P. Zheng, L. Lan

  KEYWORDS: Solvent-Free, Nanofulids, TiO2 Nanoparticles, Liquid-Like Behave

  JOURNAL NAME: Soft Nanoscience Letters, Vol.1 No.2, April 8, 2011

  ABSTRACT: TiO2 nanoparticles with surface hydroxyl groups are treated by trimethoxysilane (CH3O)3Si(CH2)3O(CH2CH2O)6-9CH3 and a inorganic core/organic shell hybridmaterials, which shows itself a yellow viscous fluid, is obtained. We call it solvent-free TiO2 nanofliuds. Transmission electron microscopy (TEM), Fourier transform infrared spectrum (FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and rheometer are adopted to characterize the product. As a result, the content of TiO2 nanoparticles in the nanofliuds is about 5.5wt%, the functionalized TiO2 nanoparticles possess better dispersion, very low viscosity and an obvious liquid-like behavior at room temperature in absence of solvent.